I am trying to stop Options from going into Alphabetical order as I have a very specific store which requires users to select each option that they want, but when it's in alphabetical order this does not work correctly as they will get confused.
I want to set the options in the order I want.
Is this possible?
Yes, it is possible. Please go to EShop -> System -> Configuration -> Sorting tab, you will see the configure option to select sorting type for Options there.